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[Publication]: Accelerated photocatalytic degradation of iohexol over Co3O4/g-C3N4/Bi2O2CO3 of p-n/n-n dual heterojunction under simulated sunlight by persulfate

Prof. Shaogui Yang and Prof. Huan He published a research paper in Applied Catalysis B: Environmental (2021, 119847)

https://doi.org/10.1016/j.apcatb.2020.119847

A novel Co3O4/g-C3N4/Bi2O2CO3 (BCCN) photocatalyst with p-n/n-n heterojunction was synthesized through a solvent-thermal method. The degradation efficiency of 20mg/L iohexol reached 94% in 60min (kapp =0.0417min-1) in BCCN/light/PS system, which was 2.8 and 6.5 times higher than systems of BCCN/light (kapp =0.0150min-1) and BCCN/PS (kapp =0.0064min-1). The g-C3N4 addition lowered conduction band of the prepared material to produce superoxide radicals, activate persulfate and further prevent the recombination of photoelectrons and holes. Superoxide radicals and singlet oxygens were dominant radicals for iohexol degradation. Besides, persulfate could act as electron acceptor to enhance efficiency of electron transfer. The interaction between sulfate, superoxide and hydroxyl radicals improved singlet oxygens production. Furthermore, theoretical calculation and liquid chromatography mass spectrometry were performed to analyze degradation pathway of iohexol in the system. Ultimately, the BCCN/light/PS system can provide a new method to degrade organic pollutants in aquatic environments.